{2-Bromo-4-chloro-6-[2-(diethylamino)ethyliminomethyl]phenolato-κ3 N,N′,O}(thiocyanato-κN)copper(II)
نویسندگان
چکیده
In the title compound, [Cu(C(13)H(17)BrClN(2)O)(NCS)], the Cu atom is in a slightly distorted square-planar geometry, coordinated by the three donor atoms of the ligand and the N atom of the isothio-cyanate group.
منابع مشابه
Di-μ-thiocyanato-bis({2,4-dichloro-6-[2-(diethylamino)ethyliminomethyl]phenolato}copper(II))
The title compound, [Cu(2)(NCS)(2)(C(13)H(17)Cl(2)N(2)O)(2)], was obtained by the reaction of 3,5-dichloro-salicylaldehyde, N,N-diethyl-ethane-1,2-diamine, sodium thio-cyanate, and copper(II) acetate in an ethanol solution. It crystallizes as a centrosymmetric dimer with a very long Cu⋯S axial bond [2.972 (3) Å]. The Cu atom is five-coordinated by the three donor atoms of the Schiff base ligand...
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In the title mononuclear copper(II) complex, [Cu(C(12)H(17)N(2)O(2))(NCS)], the Cu(II) atom is four-coordinated by an NNO-donor set of the tridentate Schiff base ligand and the N atom of a terminal thio-cyanate ligand in a slightly distorted square-planar geometry.
متن کامل(Dimethylformamide-κO)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ3 N,N′,O 1](thiocyanato-κN)copper(II)
In the title compound, [Cu(C(14)H(13)N(2)O(2))(NCS)(C(3)H(7)NO)], the Cu(2+) ion is coordinated by an N,N',O-tridentate 2-meth-oxy-6-(2-pyridylmethyl-imino-meth-yl)phenolate ligand, an N-bonded thio-cyanate ion and an O-bonded dimethyl-formamide (DMF) mol-ecule, resulting in a distorted CuN(3)O(2) square-based pyramidal geometry for the metal ion, with the DMF O atom in the apical site. The dih...
متن کامل(Acetato-κO)(2-bromo-6-{[3-(dimethylazaniumyl)propylimino-κN]methyl}phenolato-κO)(thiocyanato-κN)zinc
In the title compound, [Zn(CH(3)COO)(NCS)(C(12)H(17)BrN(2)O)], the Zn(II) atom is four-coordinated in a distorted tetra-hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of an acetate ligand and one thio-cyanate N atom. In the crystal, mol-ecules are linked via pairs of N-H⋯O hydrogen bonds, forming inversion dimers.
متن کاملChlorido[4-chloro-2-(pyridin-2-ylmethyliminomethyl)phenolato-κ3 N,N′,O]copper(II)
In the title complex, [Cu(C(13)H(10)ClN(2)O)Cl], the Cu(II) ion is coordinated by one O atom and two N atoms of the tridentate Schiff base ligand and one chloride ion, forming a slightly distorted square-planar geometry. Weak Cu⋯Cl inter-actions [2.793 (5) Å] result in the formation of a chain along the a axis.
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